11
Nano-Modification of Building Composite Structures
DOI: http://dx.doi.org/10.5772/intechopen.86388
It is worth emphasizing that the experimentally obtained
lowest EEA value
(61.7 kJ/mol) corresponds to the use of a complex modifying additive based
on nano-sized SiO
2
particles in combination with a superplasticizer. This
is explained
by the fact that, unlike carbon nanotubes, SiO
2
nanoparticles are
related to the mineral phases of hardening cement neoplasms with a crystal-
chemical structure that facilitates the formation of molecular clusters and
nuclei
on SiO
2
nanoparticles as active crystallization centers. We draw attention here
to the fact that the accelerating role of the additive takes place, despite the fact
that the surfactant present in the complex additive slows down the hydration
processes.
Analyzing
the results of kinetic studies, it is necessary to address the question of
the feasibility of combining the factor of introducing additives of nano-modifiers
with the temperature factor accelerating the process of cement hydration. And in
this regard, we will review the data obtained on the values of the temperature coef-
ficient of the reaction rate (α(Т)) (see
Figure 2).
Specimen ID
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