Simulation rate of reaction – iodine clock


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Simulation rate of reaction


Simulation rate of reaction – iodine clock
The iodine clock reaction is a so called non-continuous method of detecting change during a reaction. In this activity you are going to investigate the effect of concentration and temperature on the rate of reaction of the “iodine clock” reaction.
The reaction you are going to investigate is
2I-(aq) + S2O82-(aq)  I2(aq) + 2SO42-(aq) Reaction 1

I2(aq) + 2S2O32-(aq)  2I-(aq) + S4O62-(aq) Reaction 2

I2(aq) + (C6H10O5)n  H2O  blue complex Reaction 3
In summary, iodide (I-) and persulfate ions (S2O82-) react to produce iodine (I2) and sulphate ions (SO42-) in reaction (1). This iodine is immediately consumed by the thiosulfate ions (S2O32-) in a pathway described by reaction (2). As soon as all of the S2O32-ions are consumed, the excess iodine produced in (1) is free to react with starch, turning the solution blue (3). The amount of thiosulfate ions added tells how much iodine had been produced in the time taken for the reaction to turn blue.
Perform the simulation

http://introchem.chem.okstate.edu/DCICLA/iodine_clock.html


  1. Use the setting in the simulation for concentrations of I- and S2O82-, 25°C. Perform the simulation 5 times or until the time taken for the reaction to occur don´t vary more than 0.01s.

  2. Change the concentration of I- and determine the time taken for the reaction to occur as above.

  3. Change the concentration of S2O82- and determine the time taken for the reaction to occur as above.

  4. Use the original setting and investigate how temperature affects rate of reaction.

Result: Write down the results in a table. Draw a graph using the data from the temperature simulations. Calculate the rate of reaction.



The report will be assessed on An, Ev and Comm.
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