′-((2-methoxy-naphthalene-1-yl)methylene) pyrimidine-5-carbohydrazide (H5) and
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4 ConclusionsThe results from all experiments demonstrated that the percentage of inhibition for carbon steel corrosion rises with increasing the (H4 & H5 & H6) concentrations, the percentage of inhibition is also increasing with increasing temperatures. The adsorption of compounds molecules on the carbon steel surface is due to Temkin isotherm. Tafel polarization results demonstrate that (H4 & H5 & H6) appears as mixed type inhibitor. The inhibition efficiencies examined by different techniques are in acceptable agreement. The FT-IR and XPS examination assured the foundation of a protective layer of (H4 & H5 & H6) on carbon steel surface. The investigated compounds which have shown inhibition efficiency greater than 90% are the most suitable inhibitors for any industrial application as corrosion inhibitors of carbon steel. The investigation by Monte Carlo Simulation substantiates the experimental results. The inhibition efficiency can be arranged in the following order H6 > H4 > H5. FundingThis study did not obtain any external funding. Conflicts of interestThere are no conflicts to declare. AcknowledgementsMany thanks to Dr/Hala Refaat (professor of organic chemistry-faculty of science-El-Arish University) for synthesizing & providing the investigated compounds. ReferencesG. H. Koch, M. P. H. Brongers, N. G. Thompson, Y. P. Virmani and J. H. Payer, in Handbook of environmental degradation of materials, Elsevier, 2005, pp. 3–24 Search PubMed. S. A. Ali, M. T. Saeed and S. U. Rahman, Corros. Sci., 2003, 45, 253–266 CrossRef. E. Machnikova, K. H. Whitmire and N. Hackerman, Electrochim. Acta, 2008, 53, 6024–6032 CrossRef CAS. M. Benabdellah, R. Touzani, A. Aouniti, A. Dafali, S. El Kadiri, B. Hammouti and M. Benkaddour, Mater. Chem. Phys., 2007, 105, 373–379 CrossRef CAS. A. Fiala, A. Chibani, A. Darchen, A. Boulkamh and K. Djebbar, Appl. Surf. Sci., 2007, 253, 9347–9356 CrossRef CAS. R. A. Prabhu, T. V. Venkatesha, A. V. Shanbhag, G. M. Kulkarni and R. G. Kalkhambkar, Corros. Sci., 2008, 50, 3356–3362 CrossRef CAS. R. A. Prabhu, A. V. Shanbhag and T. V. Venkatesha, J. Appl. Electrochem., 2007, 37, 491–497 CrossRef CAS. J. Z. Ai, X. P. Guo, J. E. Qu, Z. Y. Chen and J. S. Zheng, Colloids Surf., A, 2006, 281, 147–155 CrossRef CAS. G. Ji, P. Dwivedi, S. Sundaram and R. Prakash, Ind. Eng. Chem. Res., 2013, Download 0.89 Mb. Do'stlaringiz bilan baham: |
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