Making isotopes matter: Francis Aston and the mass-spectrograph Jeff Hughes
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- 1. Introduction
- 2. From bottlewasher to gentleman-researcher: Francis Aston at the Cavendish laboratory
Making isotopes matter: Francis Aston and the mass-spectrograph Jeff Hughes Centre for the History of Science, Technology and Medicine. University of Manchester. jeff.hughes@manchester.ac.uk Dynamis
Fecha de recepción: 22 de febrero de 2008 [0211-9536] 2009; 29: 131-165 Fecha de aceptación: 23 de julio de 2008 SUMMARY: 1. ―Introduction. 2.―From bottlewasher to gentleman-researcher: Francis Aston at the Cavendish laboratory. 3. ―Negotiating the nuclear atom: Rutherford, Bohr and Soddy. 4. ―From positive rays to mass-spectrograph: Aston and the element of surprise. 5.―Ruther- ford, Aston and the constitutive role of the mass-spectrograph. 6. ―The Nobel Prizes and the history of isotopes. 7. ―Conclusion. ABSTRACT: Francis Aston «discovered» the isotopes of the light elements at the Cavendish Laboratory in 1919 using his newly devised mass-spectrograph. With this device, a modi- fication of the apparatus he had used as J.J. Thomson’s lab assistant before the war, Aston was surprised to find that he could elicit isotopes for many of the elements. This work was contested, but Rutherford, recently appointed to head the Cavendish, was a strong supporter of Aston’s work, not least because it supported his emergent programme of re- search into nuclear structure. This paper will explore Aston’s work in the context of skilled practice at the Cavendish and in the wider disciplinary contexts of physics and chemistry. Arguing that Aston’s work was made significant by Rutherford ―and other constituencies, including chemists and astrophysicists ― it will explore the initial construction of isotopes as scientific objects through their embodiment in material practices. It will also show how the process of constructing isotopes was retrospectively reified by the award to Aston of the 1922 Nobel Prize for Chemistry. PALABRAS CLAVE: Espectrógrafo de masas, Francis Aston, J.J. Thomson, Frederick Soddy, Premios Nobel, isótopos, laboratorio Cavendish. KEY WORDS: Mass-spectrograph, Francis Aston, J.J. Thomson, Frederick Soddy, Nobel Prizes, isotopes, Cavendish laboratory. «I will now read to you the state of affairs as it will doubtless be recor- ded by the historian of the future. In 1914 orthodox chemists were faced with a crisis of unprecedented gravity. Their centenarian ruler, the venerable Postulate of Dalton, was lying dangerously ill with lead poisoning and one
Jeff Hughes Dynamis 2009; 29: 131-165 132 of their brightest young protégés, Neon, a member of that most exclusive and aristocratic group known as the Noble gases, was strongly suspected of leading a double life» 1 .
history of discoveries in our own time with which we are completely familiar makes one hesitate to believe there can be any truth in history as recorded by the historian at all, a thought that explains much (...) So easy is it to fall into the error of thinking that things which look obvious after a discovery were just as obvious before» 2 . 1. Introduction In early December 1922, after weeks of worry about travel arrangements and top-hats, the Oxford chemist Frederick Soddy and the Cambridge physicist Francis Aston sailed from Newcastle for Bergen, Christiania and Stockholm. Accompanied by Soddy’s wife and Aston’s two sisters, they were en route to the glittering annual Nobel Prize ceremony to receive the 1921 and 1922 Nobel Chemistry Prizes respectively. On an icy 10 December, they sat stiffly on the platform in Stockholm’s Musical Academy. Following a performance of Sibelius’ Elégie, they duly received their awards from King Gustav. For the reserved 1921 Prize, Soddy was cited for «his contributions to our knowledge of the chemistry of radio- active substances, and his investigations into the origin and nature of isotopes». For the 1922 award, Aston was commended «for his discovery, by means of his mass-spectrograph, of isotopes in a large number of non-radioactive elements, and for his enunciation of the whole-number rule». The awards have been taken by many, then and since, as the final and conclusive act in the drama constituting the discovery of the isotopic nature of the elements, the apparent solution to the century-old conun- drum of non-integral atomic weights. As H.G. Söderbaum, Secretary of the Swedish Academy of Sciences put it, «with the theory of isotopes 1. F. W. Aston papers. Cambridge University Library. MS Add.8322, unnumbered and undated pencil fragment. 2. Soddy, F. to Noyes, W.A. 22 February 1936. F. Soddy papers. Bodleian Library, Oxford. f. 233.
Making isotopes matter: Francis Aston and the mass-spectrograph Dynamis 2009; 29: 131-165 133 one can say with Hamlet: “this was sometime a paradox, but now the time gives it proof ”» 3 . For Aston, his sister Helen later recalled, the call to Stockholm was «like a fairy story in which all good things came true, for him the pride of achievement, and for us reflected glory in a measure of which we had never dreamed (...) Stockholm has been the city of our dreams ever since, set in a place apart from anywhere else in all our memories» 4 . Certainly, the scale of the achievement was magnificent, and Soddy and Aston kept elevated intellectual company: at the same Stockholm ceremony, Niels Bohr received the 1922 Nobel Physics Prize while Albert Einstein was cited for the reserved 1921 Physics award. Yet there are reasons to suppose that Helen Aston’s remarks were more than affected modesty on her brother’s behalf. Ernest Rutherford, head of the Cavendish Laboratory in Cambridge, leading radioactivist and Aston’s mentor and promoter betrayed his confu- sion after the award announcements when he told his confidant Bohr that «Aston’s success was of course very satisfactory but I was a little surprised for I [know] Soddy —he must appear necessarily— I had not noticed they had two years ‘Chemistry’ to fill up as well as Physics» 5 . Himself Nobel Prizeman in Chemistry in 1908 for his work in radioactivity and a leading player in the politics of the new subject, Rutherford had nominated his erstwhile co-worker Soddy several times for the Chemistry award since 1918, but had never nominated Aston and clearly did not see his Cambridge colleague as a Nobel Prize candidate. Rather, Rutherford regarded Aston as a diligent and assiduous experimentalist with considerable practical skills but little conceptual insight into atomic physics. In one sense, it is the surprise shown by Aston, his sister and Rutherford towards Aston’s Nobel award which is the subject of this paper. Some Nobel awards have occasioned enduring controversy among both historians and scientists. The 1923 Physiology-Medicine Prize, for example, has long been surrounded by debate over the precise role of co- winner J.J.R. Macleod in the discovery of insulin and the correctness of the 3. Söderbaum, H. G. Presentation Speech to F. Soddy. In: Nobel Lectures in Chemistry, 1901-1921. Amsterdam-London-New York: Elsevier; 1966, p. 367-370 (369). 4. Aston, Helen, quoted in Hevesy, G. Francis William Aston. Obituary Notices of Fellows of the Royal Society. 1948; 5: 635-650 (645). 5. Rutherford, Ernest to Bohr, Niels. 20 November 1922. Ernest Rutherford papers. Cambridge University Library. MS Add.7653.
Jeff Hughes Dynamis 2009; 29: 131-165 134 Nobel Institution’s decision 6 . Surprise, however, does not figure large in the recent historiography of the Nobel Prizes. Elisabeth Crawford has amply demonstrated the importance of academic politics, professional networks, personal ambitions and animosities, and the ideologies of nationalism and internationalism in framing Nobel science prize decisions, as well as the impact of the awards on the public and the scientific community 7 . Crawford and Robert Marc Friedman have also demonstrated the importance of the Swedish academic context in defining the scope of the science prizes and the disciplinary politics of the Nobel Committees charged with selecting nominators and evaluating nominations for the Nobel awards 8 . From this work, it is clear that Stockholm physical chemist Svante Arrhenius was the éminence gris behind the Nobel physics and chemistry prizes in the first decade of the twentieth century, particularly his role in preferentially promoting atomic research and (paradoxically) in preventing the award of a Prize to Walther Nernst for many years. Indeed, Arrhenius was a key player in the disciplinary discussions bridging chemistry and physics which under- lay the award of the 1908 Nobel Chemistry Prize to Rutherford 9 . In that sense, the historiography of the Nobel science prizes overlaps significantly with the historiography of atomic research in the early twentieth century. Despite this work on the ideology and politics of the Nobel Prizes, however, there is little explicit work on the ways in which the Prizes have interacted with and helped shape the scientists and the sciences they nomi- nally reward. Even in the 1930s, one physicist —a fluid dynamicist— com- plained that the Nobel Prizes contained a self-perpetuating bias towards 6. Broad, William. Toying with the Truth to Win a Nobel. Science. 1982; 217: 1120-1122. 7. Crawford, Elisabeth. The beginnings of the Nobel Institution. The Science Prizes, 1901-1915. Cambridge: University Press; 1984; Crawford, Elisabeth. Nationalism and internationalism in science, 1880-1939. Four studies of the Nobel population. Cambridge: University Press; 1992.
8. Crawford, Elisabeth; Friedman, Robert Marc. The Prizes in Physics and Chemistry in the context of Swedish science. In: Bernhard, C. G.; Crawford E.; Sörbom, P., eds. Science, technology and society in the time of Alfred Nobel. Oxford: Pergamon Press; 1982, p. 311-331. Friedman, Robert Marc. Nobel Physics Prize in Perspective. Nature. 1981; 292: 793-798; Friedman, Robert Marc. Friedman, Robert Marc Text, context and quicksand: Method and understanding in studying the Nobel Science Prizes. Historical Studies in the Physical and Biological Sciences. 1989; 20: 63-77. 9. Crawford, Elisabeth. Arrhenius, the atomic hypothesis, and the 1908 Nobel Prizes in Physics and Chemistry. Isis. 1974: 75: 503-522; Crawford, Elisabeth. Arrhenius. From ionic theory to the greenhouse effect. Canton, MA: Science History Publications; 1996, p. 233-237. Making isotopes matter: Francis Aston and the mass-spectrograph Dynamis 2009; 29: 131-165 135 «atomic physics», and it has been argued that this bias has persisted to the present 10
. Certainly, in recent popular scientific culture, the linkage between the Nobel science prizes, the reductionist project in twentieth century science, priority and, not least, scientific ego, has been a strong one, naturalised by Gary Taubes» Nobel Dreams and other accounts 11 .
scant attention to the 1921 and 1922 Nobel Chemistry awards. Typically, they have seen them as the appropriate reward for a sequence of self- evident scientific achievements beginning with Soddy’s articulation of the principle of isotopy for the radioactive elements in 1913, and culminating with Aston’s demonstration of the ubiquity of isotopy in the periodic table in 1919 and 1920. In many ways, this lack of critical analysis is typical of a received his- toriography which frames the history of early twentieth-century atomic and nuclear physics as a linear, teleological sequence usually beginning with the discovery of x-rays in 1895 and leading through the discovery and elaboration of radioactivity, the discovery of the electron, the articulation of the nuclear theory of the atom, wave mechanics, the discovery of the neutron, artificial radioactivity to nuclear fission. The end-point towards which this sequence extends is the atomic bomb, and it is the phenomena of nuclear weapons and nuclear power which invest this history with its meaning and significance. In this canonical and essentially retrospective account, the discovery of isotopes mark a significant point because of their role in «clarifying» nuclear structure and, of course, because of the later significance of isotopes in the release of nuclear energy 12
. Faced with such a powerful material vindication of the received his- torical account, historians have been loath to delve more deeply and offer more critical accounts of the historical development of nuclear science. This 10. Batchelor, George. The life and legacy of G. I. Taylor. Cambridge: Cambridge University Press; 1996, p. 185. 11. Taubes, Gary. Nobel dreams: Power, deceit and the ultimate experiment. New York: Random House; 1986; Singh, Rajinder; Riess, Falk. The 1930 Nobel Prize for Physics: A close decision? Notes and Records of the Royal Society of London. 2001; 55 (2): 267-283. See also the treat- ment of the Nobel Physics Prize in Kragh, Helge. Quantum generations. A history of Physics in the twentieth century. Princeton: Princeton University Press; 1999, p. 427-439. 12. For a development of this argument, see Hughes, Jeff. Radioactivity and Nuclear Physics. In: Nye, M. J., ed. The Cambridge History of Science. Vol. 5. Modern physical and mathematical sciences. New York: Cambridge University Press; 2002, p. 350-374. Jeff Hughes Dynamis 2009; 29: 131-165 136 reticence —one might even say complacency— has significant implications for our understanding of the Nobel Prizes, for in the fields of atomic and nuclear physics and chemistry, Nobel awards can appear in this teleological perspective as ratifications of well-defined and self-evident achievements. The emergence of the isotope interpretation of matter has come to be seen by scientists and historians alike as the correct solution to the long-standing problem of non-integral atomic weights and the outcome of several years of work in which Aston’s experimental work «affirmed» and generalised a particular conception of matter put forward by Soddy. 13 In this paper I argue for a much more interpretative and open-ended historical approach both to the sequence of events which by 1922 had come to constitute the «discovery» of isotopes and to the awards of Nobel Prizes to their «discoverers». Against the canonical account, I suggest that the isotope interpretation of matter as developed by Soddy to explain particular phenomena in radiochemistry was deliberately and contingently linked by him to results emerging from the quite distinct area of gas-discharge research in an effort to make his «isotopes» more plausible. This contingent accomplishment in turn became intimately bound up with the elaboration of the Rutherford-Bohr nuclear model of the atom from 1913. By following Aston’s career trajectory from 1913 to 1922, I shall then show that, though a gifted experimentalist, Aston allowed his work to be appropriated by others to support their own theories, and that he, in turn, used those theories to legitimate and give meaning to his own work. In 1919, when Aston created his mass-spectrograph, he was surprised at the nature and quantity of the results it produced: those results were interpreted by others in terms of the nuclear atomic theory, and Aston fell in with this interpretation, adopting it as his own. For a wide scientific public in the early 1920s, Aston became closely identified not just with the mass-spectrograph and its experimental pro- ducts —ever-increasing numbers of isotopes of the light elements— but with the nuclear model of the atom promoted by Rutherford’s Cavendish. In his influential 1922 monograph Isotopes, Aston promulgated an account in which he endowed isotopes with a pre-history beginning with Prout, and now squarely explained his work in terms of the nuclear atom. When the Nobel Chemistry Committee made their decision in 1922 to make awards
13. Bruzzaniti, G.; Robotti, N. The affirmation of the concept of isotopy and the birth of mass spectrography. Archives Internationales de l’Histoire des Sciences. 1989; 39: 309-334. Making isotopes matter: Francis Aston and the mass-spectrograph Dynamis 2009; 29: 131-165 137 to Soddy and Aston, they were ratifying not just the «discovery of isotopes» but also the nuclear theory of the atom which both offered a rationale for the existence of isotopes and, paradoxically, drew on isotopes for proof of its validity. Moreover, I argue that the Nobel Prize citations themselves aided and abetted a thoroughly retrospective reading of Aston and Soddy’s achievements, for they carefully historicise the work of the recipient, usually framing it in a long timescale and making it seem the inevitable outcome of the subject’s work. In framing the 1921 and 1922 Chemistry awards, the Nobel Committee not only powerfully intervened to endorse and promote a particular conjunction of theoretical and experimental work, but created a particular form of historical account to achieve a discursive closure. In conclusion, I shall question the notion of authorship in scientific discovery and explore the paradox raised by the award of a Nobel Prize to a person for someone else’s interpretation of their work and, I hope, raise searching questions about the nature of scientific achievement and the role of the Nobel Prizes in promoting it.
In order to understand the Nobel Chemistry committee’s violation of his- tory and Rutherford’s surprise, we must understand something of Francis Aston’s background. Born in 1877 into a well-off Birmingham family, Aston had studied physics and chemistry at Mason College, Birmingham, under John Poynting, William Tilden and Percy Frankland. Alongside his studies he pursued private «research» in a makeshift workshop and laboratory at his father’s house, becoming an «accomplished, if self-taught experimenter and a skilled glass-blower» 14
. Following the sensational discovery of X-rays, Aston became interested in gas-discharge experiments and X-ray tubes. Aided by books like Salomon’s popular Experiments with Vacuum Tubes he began to research intensively on high-vacuum physics using a Sprengel pump and a home-wound X-ray coil. After a period working in a Wolver- hampton brewery, during which he continued to work on gas discharges in his spare time with an automatic Töpler pump of his own design, Aston 14. Feather, N. Aston, Francis William. DNB 1941-1950, p. 24-26 (24). Jeff Hughes Dynamis 2009; 29: 131-165 138 returned to Birmingham University (as Mason College had now become) with an Associateship of the Institute of Chemistry research scholarship, and spent the next five years making «sound, if unhurried progress» on gas discharges 15
. Aston arrived at the Cavendish Laboratory in January 1910 to take up a post as research assistant to the then director, J.J. Thomson. Follow- ing his elaboration of the negative corpuscle of electricity in 1897 and after, increasingly by 1910 regarded as the «discovery of the electron», Thomson was then engaged on a series of experiments on positive rays in gas discharges, designed to elucidate the nature and character of positive electricity 16 . In practice, however, the experiments had been deeply troublesome, even with the assistance of Ebenezer Everett and Aston’s predecessor George Kaye. Aston brought his subtle technique and manipulative skills to bear on Thomson’s experiments. As Isobel Falconer has shown, the hallmark of Aston’s work was perseverance and the systematic, goal-directed modification of a single experimental design or piece of apparatus in order to obtain definite, stable and reproducible effects 17
. As part of this trial-and-error approach to experimentation, Aston introduced a series of modifications to Thomson’s apparatus, allowing characteristic positive rays to be elicited and photographically recorded for every atomic species in the discharge bulb 18 . Following this achievement, Thomson began to see in the slender photographic traces which could now be obtained «a valuable means of analysing the gases in the tube and determining their atomic weights» 19
. 15. Feather, n. 14, p. 25. 16. For recent discussions of the negative corpuscle and the «discovery» of the electron, see Falconer, Isobel. Corpuscles, electrons and cathode rays: J. J. Thomson and the «Discovery of the Electron». British Journal for the History of Science. 1987; 20: 241-276. 17. Falconer, Isobel. Theory and experiment in J. J. Thomson’s work on gaseous discharges [Ph.D. Dissertation]. University of Bath; 1985, p. 106-113; Falconer, Isobel. J.J. Thomson’s work on positive rays, 1906-1914. Historical Studies in the Physical Sciences. 1988; 18: 265-310. 18. Thomson, J. J. A New method of chemical analysis. Notices of the Proceedings of the Royal Institution. 1911; 20: 140-148; Thomson, J. J. Application of positive rays to the study of chemi- cal reactions. Proceedings of the Cambridge Philosophical Society 1911; 16: 455; Thomson, J. J. Further experiments on positive rays. Philosophical Magazine. 1912; 24: 209-253; Thomson, J. J. Rays of positive electricity. London: Longmans, Green & Co.; 1913. 19. Thomson, J. J. Rays of positive electricity. Philosophical Magazine. 1910; 20: 752-767 (758). Making isotopes matter: Francis Aston and the mass-spectrograph Dynamis 2009; 29: 131-165 139 With Aston, then, Thomson developed the positive-ray technique as a method of chemical analysis 20
. In 1912, using their «positive ray spec- trograph», Aston and Thomson found that neon, the rare gas discovered only a decade or so earlier by William Ramsay, yielded not one but two positive ray traces, corresponding to atomic weights of 20 and 22 21 . Thinking that they had discovered a new element, which they christened «meta-neon», apparently after a new element predicted by the theosophists Annie Besant and Charles Leadbeater in their 1908 book Occult Chemistry, Aston em- barked upon a series of attempts to separate the new element from neon 22 .
independently on this project of his own, while J.J. Thomson continued his investigations of the rarer species found in the positive-ray spectrograph, particularly the unusual «X 3 ». Characteristically, Aston’s project was highly empirical. Using fractional distillation and diffusion methods, he sought to separate neon and its heavier congener. He reported his results at the annual meeting of the British Association for the Advancement of Sci- ence in Birmingham in September 1913, presenting evidence to show that «atmospheric neon is not homogeneous, but consists of a mixture of two elements of approximate atomic weights 19.9 and 22.1 respectively». The lighter of these was true neon, the heavier the new gas meta-neon, present in atmospheric neon to between 10 and 15%. Aston concluded that he had «a very strong case for the view that atmospheric Neon is not an element but a mixture of two» 23 .
discovered a new element. In addition to the remarkable role of Besant and Leadbeater’s Occult Chemistry in providing the conceptual resources to interpret the new neon trace and to bring «meta-neon» into laboratory culture, the idea that atmospheric neon might consist of yet further «hidden» 20. Aston, F. W. Sir J. J. Thomson’s new method of chemical analysis. Science Progress. 1912; 7: 48-65.
21. On the background to the discovery of the rare gases, see Hirsh, R. F. A Conflict of principles: The discovery of Argon and the debate over its existence. Ambix. 1981; 28: 121-130. 22. Aston, F. W. On the homogeneity of atmospheric Neon. Unpublished and undated typescript. Aston papers. Almost certainly Aston’s paper to the British Association for the Advancement of Science, 1913. Besant, Annie; Leadbeater, Charles. Occult chemistry: A series of Clairvoyant observations on the chemical elements. London: Theosophical Publishing House; 1908, p. 83. 23. Aston, n. 22, p. 11-12. Jeff Hughes Dynamis 2009; 29: 131-165 140 elements was a credible one. Like the other «noble» gases, neon itself had only been discovered a decade or so earlier on the basis of subtle physical measurements, and had been accommodated by extending the periodic table to create a new group. It was entirely plausible to suppose that further elements might be found, perhaps using the even more subtle traces of the positive-ray spectrograph. The difficulty with this view, however, was that conventional spectroscopic analysis failed to show a distinct optical spectrum for the new gas. By 1913 the spectroscope was, according to Aston, «an instrument which until very lately, has been regarded not only as the most prolific source of the discovery of new elements but also as an infallible means of their identification» 24 . Its inability to adjudicate in the neon case was not irreparable, however; Aston put forward two possible explanations to account for the spectroscope result: «Either Metaneon is a gas like Oxygen of which the spectrum is easily swamped and can only be brought out in the absence of preponderating quantities of other gases; or its spectrum is identical with that of Neon». The first explanation ap- pealed to precedent and spectroscopic practice; the second he regarded as «fundamental and revolutionary» 25
. Aston had not arrived at this second suggestion unaided: he noted that «I am informed by Mr. N. Bohr that on certain aspects of the Nucleus Atom theory of Rutherford, he is led to the conclusion that if Metaneon exists its spectrum not only may, but of necessity must be identical with that of Neon»
26 . Aston’s invocation of Bohr is highly significant, and to understand it we must now turn to developments elsewhere which provided resources for Aston to reframe and reinterpret his work and link it concerns out with the Cavendish Laboratory.
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