Modeling and approval of vinyl acetate synthesis process from acetylene
-m=6.5, the dependence of the velocity of the steam-gas mixture on the criterion
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Maqola 1 Nazarov
2-m=6.5, the dependence of the velocity of the steam-gas mixture on the criterion
Depending on the speed of the steam-gas mixture, this velocity has a certain character. Limitations on control parameters (T, m, W0) are set in industrial devices, we determine the effect of these limitations on the most favorable conditions. In our case, since the rate increases with temperature, it is necessary to keep the temperature high. At the end of the cycle, the temperature will inevitably rise to -2300. It should be noted that the effect of the temperature limitation on the measured quantities is not very important. 8 Figure 8. Effect of velocity limitation of vapor-gas mixture on the optimal regime: Wo1, m1, Xk1, - with velocity limitation, Ԝ=10 mol/sec.m2 Wo2, m2, Xk2 - unlimited The size of m and W0 parameters obtained with speed restrictions (W0≤Wonp) is larger than the size of parameters obtained without restrictions. Despite this, the difference in these measurements is not very significant. CONCLUSIONS A mathematical model of the process was obtained by changing the catalyst activity. The experimental parameters obtained in the experimental reactor are well described by the model. The internal diameter of the tube was calculated under the condition of maximum permissible parametric sensitivity. The approval process has been completed. The production yield of vinyl acetate was accepted as the acceptance criterion. The maximum principle is used to solve the problem. Optimum plots of temperature, molar excess of acetylene, and rate of reaction mixture with time were found. Optimal temperature profile along the length of the reactor is isothermal. The analysis is carried out with the influence of the control parameters and the restrictions of the criterion types in the optimal regimes. It was found that the long service life of the catalyst is 45 days. REFERENCES Патент РФ Ха 2181356, 1977 г., Джобсон С., Ватсон Д. Д., «Объединённый способ получения винилацетата и уксусной кислоты». Опубликован БИ Ха 9, 2002 г. Романчук С. В., Козлова Г. А., Сердюк А. В. И др. //Кинетика и катализ, 1992 г., т. 4, с. 691-696. Тёмкин О. Н., Абанто-Чавез X. Й., Хоанг Ким Бонг. «Кинетические модели синтеза винилацетата на цинк ацетатных катализаторах нового поколения»//Кинетика и катализ, 2000 г., Ка 5, т. 41, с. 701-718. Абанто-Чавез X. Й.. «Новая технология приготовления цинк ацетатных катализаторов и кинетические модели синтеза винилацетата», диссертация на соискание учёной степени кандидата химических наук, М.:МЙТХТ, 1998 г. 98 с. Бояджян, В.К. Производство винилацетата на основе этилена: Учеб. пособие для рабочих профессий [Текст] / В.К. Бояджян, В.К. Ерицян, А.В. Татевосян, Г.Ш. Алавердян, С.Н. Сергеева. − М.: НИИТЭХИМ, 1987. –75 с. Варданян, Д.В. Влияние начальных условий на активность и показатели процесса получения винилацетата путем парофазного ацетоксилирования этилена [Текст] / Д.В. Варданян, В.Н. Сапунов, И.Ю. Литвинцев. Российский химико-технологический университет им. Д.И. Менделеева. –М.: 2003. -26 с. -Депонировано на ВИНИТИ 11.03.2003, №426-В2003. Варданян, Д.В. Закономерности газофазного ацетоксилирования этилена на модифицированном палладиевом катализаторе [Текст] / дис. ... канд. хим. наук: 05.17.04. –РХТУ им. Д.И. Менделеева, Москва, 2003. –134 с. Варданян, Д.В. Математическая модель процесса получения винилацетата парофазным ацетоксилированием этилена [Текст] / Д.В. Варданян, И.Ю. Литвинцев, В.Н. Сапунов [и др.] // Химическая промышленность сегодня. − 2003. −№3. −С. 50-54. Восканян, П.С. Влияние природы носителя на каталитическую активность палладиевого катализатора синтеза винилацетата газофазным ацетоксилированием этилена [Текст] // Катализ в промышленности. –2012. –№4. –С. 33-41 Восканян, П.С. Влияние содержания и соотношения активных компонентов на активность и селективность катализатора синтеза винилацетата газофазным ацетоксилированием этилена [Текст] // Катализ в промышленности. -2010. -№2. -С. 43. Fayzullaev, N.I, Bobomurodova, S.Y, Xolmuminova, D.A Physico-chemical and texture characteristics of Zn-Zr/VKTS catalyst//Journal of Critical Reviews, 2020, 7(7), стр. 917–920 F N Temirov, J Kh Khamroyev, N I Fayzullayev, G Sh Haydarov and M Kh Jalilov. Hydrothermal synthesis of zeolite HSZ-30 based on kaolin //IOP Conference Series: Earth and Environmental Science. – IOP Publishing, 2021. – Т. 839. – №. 4. – С. 042099. Khamroyev, J.K., Akmalaiuly, K., Fayzullayev, N. Mechanical activation of navbahorsk bentonite and its textural and adsorption characteristics//News of the National Academy of Sciences of the Republic of Kazakhstan, Series of Geology and Technical Sciences, 2022, 1(451), стр. 167–174. Buronov F., Fayzullayev N. Synthesis and application of high silicon zeolites from natural sources //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050004. Tursunova, N.S., Fayzullaev, N.I. Kinetics of the reaction of oxidative dimerization of methane//International Journal of Control and Automation, 2020, 13(2), стр. 440–446. Fajzullaev, N.I., Fajzullaev, O.O. Kinetic regularities in reaction of the oxidizing condensation of methane on applied oxide catalysts//Khimicheskaya Promyshlennost', 2004, (4), стр. 204–207 Muradov, K.M., Fajzullaev, N.I. Technology for producing the ethylene using the reaction of the oxidizing condensation of methane//Khimicheskaya Promyshlennost', 2003, (6), стр. 3–7 Sarimsakova, N.S., Fayzullaev, N.I., Musulmonov, N.X., Atamirzayeva, S.T., Ibodullayeva, M.N. Kinetics and mechanism of reaction for producing ethyl acetate from acetic acid//International Journal of Control and Automation, 2020, 13(2), стр. 373–382. Omanov, B.S., Fayzullaev, N.I., Musulmonov, N.K., Xatamova, M.S., Asrorov, D.A.Optimization of vinyl acetate synthesis process//International Journal of Control and Automation, 2020, 13(1), стр. 231–238 Omanov, B.S., Fayzullaev, N.I., Xatamova, M.S. Vinyl acetate production technology//International Journal of Advanced Science and Technology, 2020, 29(3), стр. 4923–4930 Fayzullayev, N.I., Umirzakov, R.R., Pardaeva, S.B. Study of acetylating reaction of acetylene by gas chromatographic method//ACS National Meeting Book of Abstracts, 2005, 229(2) Fajzullaev, N.I., Muradov, K.M. Investigation of reaction of catalytic vapor-phase synthesis of vinyl acetate on applied catalyst//Khimicheskaya Promyshlennost', 2004, (3), стр. 136–139 Fayzullayev, N.I., Umirzakov, R.R. To obtain acetone by spontaneous hydration of acetylene//ACS National Meeting Book of Abstracts, 2005, 229(2) Fajzullaev, N.I., Yusupov, D., Shirinov, Kh.Sh, Keremetskaya, L.V, Umirzakov, R.R. Catalytic vapor-phase hydration of acetylene and its derivatives//Khimicheskaya Promyshlennost', 2002, (7), стр. 34–37 Fajzullaev, N.I. Kinetics and mechanism of reaction of catalytic hydrochlorination of acetylene//Khimicheskaya Promyshlennost', 2004, (1), стр. 49–52 Aslanov, S.C., Buxorov, A.Q., Fayzullayev, N.I. Catalytic synthesis of С2-С4-alkenes from dimethyl ether// International Journal of Engineering Trends and Technology, 2021, 69(4), стр. 67–75 Xolmirzayeva H. N., Fayzullayev N. I. Obtaining Nanocarbon from Local Raw Materials and Studying Its Textural and Sorption Properties //International Journal of Engineering Trends and Technology, 2022 Volume 70 Issue 2, 163-171. ISSN: 2231 – 5381 /doi:10.14445/22315381/IJETT-V70I2P219 Bukhorov A. Q., Aslanov S. C., Fayzullaev N. I. Catalyst deactivation in synthesis of olefins below methanol //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050010. Bukhorov A. Q., Aslanov S. C., Fayzullaev N. I. Conversion of dimethyl ether to lower olefines //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050011. Bukhorov A. Q., Aslanov S. C., Fayzullaev N. I. Kinetic laws of dimethyl ether synthesis in synthesis gas //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050012. Musulmonov N. X., Fayzullaev N. I. Textural characteristics of zinc acetate catalyst //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050015. Bukhorov A. Q., Aslanov S. C., Fayzullaev N. I. Direct extraction of dimethyl ether from synthesis gas //AIP Conference Proceedings. – AIP Publishing LLC, 2022. – Т. 2432. – №. 1. – С. 050013. Download 368.61 Kb. Do'stlaringiz bilan baham: |
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