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EFFECTIVE TECHNOLOGIES FOR PROCESSING LEAD RAW
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3. EFFECTIVE TECHNOLOGIES FOR PROCESSING LEAD RAW
MATERIALS 3.1. Preparation of lead raw materials for processing 4.4 4.5 4.6 4.7 4.8 4.9 5 2016 2017 2018 2019 2020 Le ad p ro d u cti o n , m ln .t. Years 156 Because lead ores are often polymetallic sulphide ores, they are beneficiated first by collective and then by selective flotation [86-88]. Usually, lead is mainly found in the form of galena (PbS) in ore, so butyl and ethyl xanthogenates and dithiophosphate are used as collecting agents during flotation (pH=9-9.5). Sodium sulfide (Na 2 S, consumption up to 1 kg/t), potassium bichromate (K 2 Cr 2 O 7 ) and potassium chromates (K 2 CrO 4 ) are used as quenchers of galena (chromate consumption is 20-25 g /t, pH=5- 6). If copper-lead polymetallic ore is to be enriched by selective flotation, then lead sulfide H 3 PO 4 , NaH 2 PO 4 [89-91]. It is extinguished in the presence of soluble phosphates such as Ca(H 2 PO 4 ) 2 or with a mixture of sodium thiosulfate with iron sulfate (substance consumption is up to 1.7-7 kg/t) [92-94]. In addition, starch and dextrin are among the organic quenchers of galena (consumption up to 0.1-0.2 kg/t) [95]. In selective flotation of lead-copper polymetallic ore, copper sulfides are quenched with a mixture of sodium cyanide and zinc sulfate, and lead sulfides are separated using a collector. In the flotation of oxide compounds of lead, more organic fatty acids or their compounds are used, for example, compounds such as oleic acid, sodium oleate, naphthenic acids, tall oil (the composition is similar to pine oil) can be used. If the ore does [96-100] not contain iron oxides, dolomite and limestone, oxidized lead compounds are better flotation using oxyhydryl collectors. T-80 reagent is used as a foaming agent in the flotation process (consumption 10-15 g/t) [101-102]. The degree of extraction of lead in flotation enrichment is 83-94%. The preparation processes from the initial ore to the production of sulphide lead concentrate are described in detail in Fig.2. Fig.2. Processes for preparing sulphide lead ore for processing 157 Currently, a combined method of enrichment of galena compounds is used. In order to save the consumption of flotation reagents, the ore is initially processed by gravity method, 30-45% of unnecessary rocks are removed, and then the remaining sulphide part is flotation [103-107]. The approximate composition of lead enrichment obtained after flotation enrichment is as follows, %: Pb 45 – 50; Zn 4 – 14; Cu 1-3; S 15-20; Fe 4 – 15; SiO 2 - 10; Ag up to 500 g/t. Download 1.46 Mb. Do'stlaringiz bilan baham: |
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