Udc: 538. 956 Preparation of poly (methyl methacrylate)-based polymer electrolytes for solid-state for mg-ion batteries


Table1: The dimensions and composition of the prepared samples


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PREPARATION OF POLY (METHYL METHACRYLATE)-BASED POLYMER

Table1: The dimensions and composition of the prepared samples 
Sample
name 
Sample 
thickness 
(см) 
PMMA (гр) 
EC
(гр) 
MgTf
2
(гр) 
THF 
(мл)
Н1 
0.0246 


0.75 
40 
Н2 
0.0233 


0.75 
40 
Н3 
0.028 


0.75 
40 
Н4 
0.0287 


0.75 
40 
Н5 
0.0203 


0.75 
40 
Fig. 2. Stages of solid electrolyte preparation 
Preparation of electrodes of polymer-based Mg-ion batteries. The composition of the 
electrodes consists of the following materials: magnesium permanganate (MgMnO4), carbon, 
polyvinylidene fluoride (PVDF), N-methylpyrrolidone (NMP). We first extract 0.8 mg of magnesium 
permanganate (MgMnO4), 0.1 mg of carbon (C), 0.1 mg of polyvinylidene fluoride (PVDF), heat the 
MgMnO4 and carbon mixture under vacuum at 80 °C for 5 min, then add PVDF and mix. Once the 
mixture is homogeneous, add 3-4 drops of NMP solvent to it and stir the mixture at room temperature 
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Semiconductor Physics 
and Microelectronics 
Volume 3, Issue 4 
2021 
Физика полупроводников 
и микроэлектроника 
19 
for one day. Assemble the battery in the following sequence in the sandwich method from the 
prepared samples MgMnO4 / SPE / Mg metal Figure 1-b. 
Conclusion. Polymer-based Mg-ion batteries, which are safer, lighter and more compact than 
traditional Mg-ion batteries, are characterized by high energy and power density, low cost, simplicity 
of manufacturing technology and long-term non-discharge. We recommend the production of these 
batteries in our country. 
References 
[1] M. Marcinek et al., “Electrolytes for li-ion transport – Review,” vol. 276, pp. 107–126, 
2015, doi: 10.1016/j.ssi.2015.02.006. 
[2] A. Arya and A. L. Sharma, “Polymer electrolytes for lithium ion batteries: a critical 
study,” Ionics. 2017, doi: 10.1007/s11581-016-1908-6. 
[3] Y. Mg, J. Wang, J. Tang, Y. Mgu, and Y. He, “Conductive performances of solid polymer 
electrolyte films based on PVB/MgClO4 plasticized by PEG200, PEG400 and PEG600,” 
J. Power Sources, vol. 187, no. 2, pp. 305–311, 2009, doi: 
10.1016/j.jpowsour.2008.11.126. 
[4] A. Abdukarimov et al., “Characteristics of dye-sensitized solar cells (DSSCs) using liquid 
and gel polymer electrolytes with tetrapropylammonium salt,” Opt. Quantum Electron.
vol. 52, no. 3, pp. 1–15, 2020, doi: 10.1007/s11082-020-02264-1. 
[5] A. K. Arof, N. A. M. Nor, N. Aziz, and M. Z. Kufian, “ScienceDirect Investigation on 
morphology of composite poly ( ethylene oxide ) - cellulose nanofibers,” vol. 17, pp. 388–
393, 2019. 
[6] P. Yao et al., “Review on Polymer-Based Composite Electrolytes for lithium Batteries,” 
Front. Chem., vol. 7, no. August, pp. 1–17, 2019, doi: 10.3389/fchem.2019.00522. 
 
 
 
 
 

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