Умумий ва ноорганик кимё институти

 
The fifth chapter is devoted to theme «Development of novel surfactants and 
high molecular substances», i.e. development surfactants for metallurgy. 
1. The foaming flotation reagent from local anthropogenic raw materials was 
developed for enrichment sulfide ore instead of analog Т-92 (Russia). 
The following materials were applied: wastes of ethanol production of JSC 
«Navoiazot», JSC «Elektrohimzavod», LLC Sumono, polyethylene from Shurtan 
gas chemical complex. Ethyl alcohol (EA), isoamyl alcohol (IA) and crotonic 
aldehyde (CA), crotonic faction (CF), ether aldehyde fraction (EAF), fusel oil 
(FO), monobutyl ether of polyglycols (MEP), α-olefine С
10
-С
20
from a withdrawal 
of production of a low-polymeric fraction of polyethylene (LPFP) were used as 
well. Synthesis of surfactants №1-5 was carried out by CA, CF with EA, IA, EAF, 
FO (NH
4
Cl catalyst, H
2
SO
4
for vapors of CA: IA) at 75 °C.
- 1,1,3- tri ethyl butane (TEB) (CA with EA), (№1); 
- Tri isoamyl butan (TIB) (CA: IA = 1: 5 mol / mol, time 6 h.), (№2); 
- based on CF and EAF(CF: EAF = 1: 5 mol / mol, 6 h), (№3); 
- based CF and SM trimonospirtbutan (TMSB), (№4); 
- Based on propylene oxide and butyl alcohol (POBA), (№5);
- PT (olefin sulfonate) fraction C
10
-C
20
polyethylene waste, (№6); 
- A standard foaming agent T-92 (№7). 
The object of presented study was to compare the colloidal phase, flotation 
properties synthesized surfactants with analogue T-92. 
The surface-active properties were studied as well. It was established that 
surfactants №1-7 reduce the solution’s surface tension (σ). TNAB (№2) and 
TMSB (№4) had the minimum value of σ. According to surface tension of 

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surfactants, including the studied foaming agents, PT-6, PT-7, AT-3 and AT-4 
were selected which were similar to properties of the T-92 (Fig. 4). Among them 
AT-4 and PT-7 have more surface-active effect. By this effect, they have arranged 
in a row: PT-6