Chemistry and catalysis advances in organometallic chemistry and catalysis


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Document Outline

  • Cover
  • Title Page
  • Contents
  • Preface
  • Contributors
  • Part I Activation and Functionalization of Carbon Single Bonds and of Small Molecules
    • Chapter 2 Toward Functionalization of Alkanes Under Environmentally Benign Conditions
      • 2.1 Introduction
      • 2.2 Peroxidative Oxidations of Alkanes to Alcohols and Ketones, Catalyzed by Transition Metal Complexes
      • 2.3 Metal-Free Alkane Hydrocarboxylation and Related Carboxylation
      • 2.4 Final Remarks
      • Acknowledgments
      • References
    • Chapter 3 Self-assembled Multicopper Complexes and Coordination Polymers for Oxidation and Hydrocarboxylation of Alkanes
      • 3.1 Introduction
      • 3.2 Self-Assembly Synthesis in Aqueous Medium
      • 3.3 Aminoalcoholate Multicopper Complexes and Coordination Polymers
      • 3.4 Application in Alkane Oxidation
      • 3.5 Application in Alkane Hydrocarboxylation
      • 3.6 Concluding Remarks
      • Abbreviations
      • Acknowledgments
      • References
    • Chapter 4 Activation of C-O and C-F Bonds by Pincer-iridium Complexes
      • 4.1 Introduction
      • 4.2 Cleavage and Oxidative Addition Of C-O Bonds
      • 4.3 Cleavage and Oxidative Addition of C-F Bonds
      • 4.4 Summary
      • Acknowledgments
      • References
    • Chapter 5 Functionalization of sp2 and sp3 Carbon Centers Catalysed by Polyoxometalates and Metalloporphyrins
      • 5.1 Introduction
      • 5.2 Functionalization of sp3 Carbon Centers under Homogeneous Conditions
      • 5.3 Functionalization of sp2 Carbon Centers under Homogeneous Conditions
      • 5.4 Functionalization of sp2 AND sp3 Carbon Centers under Heterogeneous Conditions
      • 5.5 Final Remarks
      • Acknowledgments
      • References
    • Chapter 6 Quasi-borinium Cation Based on Cobalt Bis(dicarbollide): Its Lewis Acidity and C-H and C-X Bond Activation
      • 6.1 Introduction
      • 6.2 Quasi-Borinium Cations: Formation and Reactivity
      • 6.3 C-H Activation of Arenes
      • 6.4 C-X Activation of Halogen Alkanes
      • 6.5 Lewis Acidity of Quasi-Borinium Cation
      • References
    • Chapter 7 Transition-metal-promoted Functionalization of Carboranes
      • 7.1 Introduction
      • 7.2 [2+2+2] Cycloaddition of Ni-Carboryne with Alkynes
      • 7.3 Coupling Reaction of Ni-Carboryne with Alkenes
      • 7.4 [2+2+2] Cycloaddition of Ni-Carboryne with Activated Alkenes and Alkynes
      • 7.5 Ni-Catalyzed [2+2+2] Cycloaddition of Carboryne with Alkynes
      • 7.6 Pd/Ni-Cocatalyzed [2+2+2] Cycloaddition of 1,3-Dehydro-o-Carborane with Alkynes
      • 7.7 Reaction of Zirconocene-Carboryne with Polar Unsaturated Molecules
      • 7.8 Reaction of Zirconocene-Carboryne with Pyridines
      • 7.9 Reaction of Zirconocene-Carboryne with Alkynes and Alkenes
      • 7.10 Zr/Ni Co-Mediated [2+2+2] Cycloaddition of Carboryne with Two Different Alkynes
      • 7.11 Zr/Ni Co-Mediated [2+2+2] Cycloaddition of Carboryne with Unactivated Alkenes and Alkynes
      • 7.12 Conclusions and Perspectives
      • Acknowledgment
      • References
    • Chapter 8 Weak Interactions and M-H Bond Activation
      • 8.1 Introduction
      • 8.2 Metal Hydrides in Hydrogen Bonding
      • 8.3 Hydrogen Bonding and Proton Transfer
      • 8.4 Activation of H2 in the Metal Coordination Sphere
      • 8.5 Conclusions
      • Acknowledgment
      • References
  • Chapter 1 Organometallic Complexes as Catalysts in Oxidation of C-H Compounds
    • 1.1 Introduction
    • 1.2 Oxygenation Reactions with Oxidants other than Peroxides
    • 1.3 Oxygenation of C-H Bonds with Peroxides
    • 1.4 Conclusions and Outlook
    • Acknowledgment
    • References
  • Part II Organometallic Synthesis and Catalysis
    • Chapter 9 Complexes with Protic N-Heterocyclic Carbene (NR,NH-NHC) Ligands
      • 9.1 Introduction
      • 9.2 Complexes with NR,NH- And NH,NH-NHCS from Cyclic Ligand Precursors
      • 9.3 Complexes with NR,NH- And NH,NH-NHCs by Template-Controlled Cyclization Reactions
      • 9.4 Complexes with NR,NH-NHCs by Oxidative Addition of Azoles
      • 9.5 Conclusion
      • Acknowledgment
      • References
    • Chapter 10 Cyclopentadienyl-functionalized N-Heterocyclic Carbene Complexes of Iron and Nickel: Catalysts for Reductions
      • 10.1 Introduction
      • 10.2 Preparation of Cyclopentadienyl-Functionalized N-Heterocyclic Carbene Ligands
      • 10.3 Cyclopentadienyl-Functionalized N-Heterocyclic Carbene Complexes of Iron and Nickel
      • 10.4 Half-Sandwich Iron and Nickel NHC Complexes as Catalysts for Reductions
      • References
    • Chapter 11 Palladium-(acyclic diaminocarbene) Species as Alternative to Palladium-(nitrogen heterocyclic carbenes) in Cross-coupling Catalysis
      • 11.1 Introduction
      • 11.2 Synthetic Approaches to Palladium Complexes Bearing ADC Ligands
      • 11.3 Catalytic Applications of Palladium-(ADC)s
      • 11.4 Final Remarks
      • Acknowledgments
      • References
    • Chapter 12 Synthesis of Metallocenes Via Metathesis in Metal Coordination Spheres
      • 12.1 Introduction
      • 12.2 Polymers Bearing Metallocene Moieties by Ring-Opening Metathesis Polymerization or Acyclic Diene Metathesis Polymerization
      • 12.3 Synthesis of Metallocenes by Ring-Closing Metathesis
      • 12.4 Synthesis of Metallocenes by Cross-Metathesis
      • 12.5 Conclusions and Outlook
      • References
    • Chapter 13 Metal-mediated [2+3] Dipolar Cycloaddition to Substrates with CN Triple Bond: Recent Advances
      • 13.1 Introduction
      • 13.2 Metal-Mediated [2 + 3] DIpolar Cycloaddition to Nitriles and Isocyanides: Synthetic Studies
      • 13.3 Metal-Mediated [2 + 3] Cycloaddition to Nitriles and Isocyanides: Theoretical Studies
      • 13.4 Final Remarks
      • Acknowledgments
      • References
    • Chapter 14 Coordination Chemistry of Oxazoline/Thiazoline-based P,N Ligands
      • 14.1 Definition of Polyfunctional Ligands
      • 14.2 P,N-Chelating Ligands Based on Oxazoline/Thiazoline System
      • Summary
      • Acknowledgments
      • References
    • Chapter 15 ``Click'' Copper Catalyzed Azide-alkyne Cycloaddition (CuAAC) in Aqueous Medium
      • 15.1 Introduction
      • 15.2 CuAAC: Organic Solvents Versus Aqueous Media
      • 15.3 Final Remarks
      • Acknowledgments
      • References
    • Chapter 16 Organogold Catalysis: Homogeneous Gold-catalyzed Transformations for a Golden Jubilee
      • 16.1 Introduction
      • 16.2 Electrophilic Gold Species: Principle and Main Modes of Reactivity
      • 16.3 Gold Catalysts
      • 16.4 Gold-Catalyzed Activation of Multiple Carbon–Carbon Bonds: Functionalization by Addition of Oxygen, Nitrogen, Sulfur, or Carbon Nucleophiles
      • 16.5 Intermolecular Trapping of Reactive Organogold Intermediates
      • 16.6 Oxene and Nitrene Precursors as Nucleophiles
      • 16.7 Coupling Reactions
      • 16.8 Generation of Structural Complexity
      • 16.9 Asymmetric Catalysis
      • 16.10 Gold Catalysis and Total Synthesis
      • 16.11 Conclusion
      • References
    • Chapter 17 Vanadium(IV) Complexes Derived from Aromatic o-Hydroxyaldehydes and Tyrosine Derivatives: Catalytic Evaluation in Sulfoxidations
      • 17.1 Introduction
      • 17.2 Results and Discussion
      • 17.3 Conclusions
      • Acknowledgments
      • References
    • Chapter 18 Microwave-assisted Catalytic Oxidation of Alcohols to Carbonyl Compounds
      • 8.1 Introduction
      • 18.2 Homogeneous Catalysis
      • 18.3 Heterogeneous Catalysis
      • 18.4 Conclusions
      • References
    • Chapter 19 Oxidation of Glycerol with Hydrogen Peroxide Catalyzed by Metal Complexes
      • 19.1 Introduction
      • 19.2 Glycerol Oxidation with H2O2 Catalyzed by the Os3(CO)12/Pyridine Combination
      • 19.3 Oxidation of Glycerol with H2O2 Catalyzed by Soluble Complex [LMn(O)3MnL](PF6)2 and its Heterogenized form [LMn(O)3MnL]2[SiW12O40]
      • 19.4 Oxidation of Glycerol with TBHP or H2O2 Catalyzed by Water-Soluble Tetracopper(II) Triethanolaminate Copper Comple
      • 19.5 Conclusions
      • Acknowledgments
      • References
    • Chapter 20 Involvement of an Acetato Ligand in the Reductive Elimination Step of the Rhodium-catalyzed Methanol Carbonylation
      • 20.1 Introduction
      • 20.2 NMR and Infrared High Pressure Studies and DFT Calculations
      • 20.3 Conclusion
      • References
    • Chapter 21 Half-sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole-based Ligands
      • 21.1 Introduction
      • 21.2 Half-Sandwich Ru(II) Derivatives
      • 21.3 Half-Sandwich Rh(III) and Ir(III) Derivatives
      • 21.4 Half-Sandwich Derivatives with Acylpyrazolone Ligands
      • 21.5 Conclusions and Perspectives
      • References
    • Chapter 22 Carbon-scorpionate Complexes in Oxidation Catalysis
      • 22.1 Introduction
      • 22.2 Peroxidative Oxygenations of Alkanes
      • 22.3 Oxidation of Alkanes by Molecular Oxygen
      • 22.4 Carboxylation of Light Alkanes
      • 22.5 Baeyer–Villiger Oxidation of Ketones
      • 22.6 Final Remarks
      • Acknowledgments
      • References
    • Chapter 23 Toward Chemoselective Bioconjugative Desulfitative Catalysis
      • 23.1 Introduction
      • 23.2 Thioorganic-Boronic Acid Desulfitative Cross-Coupling
      • 23.3 Cu-Catalyzed Desulfitative Coupling
      • 23.4 Conclusion: Approaching Aqueous Desulfitative Reaction Conditions for Biological Applications
      • References
    • Chapter 24 Sulfoxide Redox Chemistry with Molybdenum Catalysts
      • 24.1 Introduction
      • 24.2 Results and Discussion
      • 24.3 Conclusions
      • 24.4 Computational Details
      • Acknowledgment
      • References
    • Chapter 25 A New Family of Zirconium Complexes Anchored by Dianionic Cyclam-based Ligands: Syntheses, Structures, and Catalytic Applications
      • 25.1 Introduction
      • 25.2 Syntheses and Molecular Structures
      • 25.3 Thermaly Induced Orthometallation and Intramolecular Hydroamination of Aminoalkenes
      • 25.4 ROP of Lactide and Cyclam Functionalization
      • 25.5 Concluding Remarks
      • Aknowledgment
      • References
    • Chapter 26 Metal-organo Multicatalysis: An Emerging Concept
      • 26.1 Introduction
      • 26.2 Cooperative Catalysis
      • 26.3 Amines as Catalysts
      • 26.4 N-Heterocyclic Carbenes as Organocatalysts
      • 26.5 Brønsted Acids as Organocatalysts
      • 26.6 Relay and Sequential Catalysis
      • 26.7 N-Heterocyclic Carbenes as Organocatalysts
      • 26.8 Brønsted Acids as Organocatalysts
      • 26.9 Conclusion
      • References
  • Part III Organometallic Polymerization Catalysis
    • Chapter 27 Coordinative Chain Transfer Polymerisations and Copolymerisations by Means of Rare Earths Organometallic Catalysts for the Synthesis of Tailor-made Polymers
      • 27.1 Introduction
      • 27.2 Basic Concepts
      • 27.3 Catalytic Systems and Their Applications in Coordinative Chain Transfer Polymerization
      • 27.4 Catalytic Systems and their Applications in Coordinative Chain Transfer Copolymerization (CCTCOP)
      • 27.5 Discussion
      • 27.6 Conclusion—Perspectives
      • References
    • Chapter 28 Charge-neutral and Cationic Complexes of Large Alkaline Earths for Ring-opening Polymerization and Fine Chemicals Catalysis
      • 28.1 Synthesis of Charge-Neutral Heteroleptic Ring-Opening Polymerization Catalysts Based on Large Alkaline Earths
      • 28.2 Synthesis of Well-Defined, Solvent-Free Cationic Complexes of the Large Alkaline Earths
      • 28.3 Immortal Ring-Opening Polymerizations of Cyclic Esters Catalyzed by Single-Site Alkaline Earth Catalysts
      • 28.4 Intermolecular Hydroamination of Activated Alkenes Catalyzed by Charge-Neutral Heteroleptic Complexes of Large Alkaline Earths
      • 28.5 Intermolecular Hydrophosphination of Styrene Catalyzed by Charge-Neutral Heteroleptic Complexes of Large Alkaline Earths
      • 28.6 Hydrophosphonylation of Aldehydes and Nonactivated Ketones by Charge-Neutral Homoleptic and Heteroleptic Complexes of Large Alkaline Earths
      • Acknowledgments
      • References
  • Part IV Organometallic Polymers and Materials
    • Chapter 29 Organometallic Polymers
      • 29.1 Introduction
      • 29.2 Metal-Backbone Organometallic Polymers
      • 29.3 Metallic-Side Organometallic Polymers
      • 29.4 Summary And Conclusions
      • Acknowledgements
      • References
    • Chapter 30 From Serendipity to Porosity: Synthesis and Reactivity of Coordination Polymers Based on Copper Trinuclear Triangular Motifs
      • 30.1 Introduction
      • 30.2 Coordination Polymers
      • 30.3 Trinuclear Triangular CuII Moieties to Build CPs
      • 30.4 Cu(pz)2-Based Coordination Polymers. A Case of “Porosity Without Pores”
      • 30.5 Concluding Remarks
      • Acknowledgments
      • Dedication
      • References
    • Chapter 31 Organometallic Nanoparticles
      • 31.1 Introduction
      • 31.2 Ruthenium
      • 31.3 Ligand-Stabilized Ruthenium Nanoparticles
      • 31.4 Iron
      • 31.5 Cobalt
      • 31.6 Conclusion
      • Acknowledgments
      • References
    • Chapter 32 Organometallic Compounds in the Synthesis of New Materials: Old Ligands, New Tricks
      • 32.1 Introduction
      • 32.2 Functionalized Alcohols as Ligands
      • 32.3 Organometallics in the Synthesis of Heterometallic Complexes
      • 32.4 Conclusions
      • Acknowledgments
      • References
    • Chapter 33 The Role of Organometallic Complexes in the Synthesis of Shaped Carbon Materials
      • 33.1 Introduction
      • 33.2 General Comments
      • 33.3 The Shapes Taken by Carbon
      • 33.4 The Catalyst–Carbon Interaction
      • 33.5 Mechanism of Carbon Growth from a Metal Particle
      • 33.6 Organometallic Catalysts and Carbon Synthesis
      • 33.7 Conclusion
      • Acknowledgments
      • References
    • Chapter 34 Metal Catalysis in Fullerene Chemistry
      • 34.1 Introduction to Fullerenes
      • 34.2 General Remarks on the Chemical Reactivity of Fullerenes
      • 34.3 Metal-Mediated Reactions in Fullerene Chemistry
      • 34.4 Asymmetric Catalysis in Fullerene Chemistry
      • 34.5 Conclusions
      • References
    • Chapter 35 Organometallic Complexes of Sumanene
      • 35.1 Introduction
      • 35.2 Organolithium Complexes of Sumanene
      • 35.3 η6-Coordination Complexes of Sumanene
      • 35.4 Concluding Remarks and Future Prospects
      • Acknowledgements
      • References
    • Chapter 36 Advances in Luminescent Tetracoordinate Organoboron Compounds
      • 36.1 Introduction
      • 36.2 Luminescent Tetracoordinate Organoboron Compounds
      • 36.3 Applications
      • 36.4 Conclusions
      • Acknowledgment
      • References
    • Chapter 37 Mechanochemistry: A Tool in the Synthesis of Catalysts, Metallodrugs, and Metallopharmaceuticals
      • 37.1 Introduction
      • 37.2 Mechanochemistry in Supramolecular Synthesis
      • 37.3 Mechanochemistry in Organic and Coordination Synthesis
      • 37.4 Mechanochemistry in Metallopharmaceuticals and Metallodrugs
      • 37.5 Mechanochemistry in Catalysis and Catalysts
      • 37.6 Conclusions
      • References
  • Part V Organometallic Chemistry and Sustainable Energy
    • Chapter 38 Organometallic Complexes for Dye-sensitized Solar Cells (DSSC)
      • 38.1 Introduction
      • 38.2 Ruthenium Complexes for DSSC
      • 38.3 Non-Ruthenium Metal Complexes for DSSC
      • 38.4 Structure of Metal Complex Sensitizers
      • 38.5 Performance Evaluation of Dye-Sensitized Solar Cells
      • 38.6 Research Development on Metal Complexes for Dye-Sensitized Solar Cells
      • 38.7 The Interaction and the Binding Mode of Dyes on TiO2 Surface
      • 38.8 Metal Complexes as Redox Mediators for DSSC
      • 38.9 Conclusion
      • References
    • Chapter 39 Synthetic Photosynthesis for the Conversion of Large Volumes of Carbon Dioxide into Energy-Rich Molecules: Saving Fossil Fuels by Recycling Carbon
      • 39.1 Introduction
      • 39.2 The Past
      • 39.3 The Present
      • 39.4 The Future: Synthetic Photosynthesis
      • 39.5 Concluding Remarks
      • References
    • Chapter 40 Ionic Liquids for Hydrogen Storage: Opportunities for Organometallic Chemistry
      • 40.1 Introduction
      • 40.2 Ionic Liquids
      • 40.3 Hydrogen Storage Materials: Hydrogen-Rich Molecules
      • 40.4 Hydrogen Storage Systems Involving Ionic Liquids
      • 40.5 Conclusion and Outlook
      • References
  • Part VI Bioorganometallic Chemistry
    • Chapter 41 Metal Carbonyls for CO-based Therapies: Challenges and Successes
      • 41.1 Introduction
      • 41.2 CO in Biology and in Therapy—Origin, Targets, and Therapeutic Potential
      • 41.3 Therapeutic Delivery of CO
      • 41.4 Final Remarks and Perspectives
      • References
    • Chapter 42 The Ferrocifen Family as Potent and Selective Antitumor Compounds: Mechanisms of Action
      • 42.1 Introduction
      • 42.2 Context and Background
      • 42.3 Ferrocene and Medicinal Chemistry
      • 42.4 Synthesis and Behavior of Ferrocifen Derivatives
      • 42.5 Synthesis and Behavior of Ferrocenophane Derivatives
      • 42.6 Ferrocenophane Transposition Products and Pinacols
      • 42.7 Formulation: Research into Nanocapsules Best Suited for in Vivo Testing of Ferrocifens
      • 42.8 Conclusion
      • Acknowledgements
      • References
    • Chapter 43 On the Track to Cancer Therapy: Paving New Ways With Ruthenium Organometallics
      • 43.1 Introduction
      • 43.2 Our Strategy in Bioorganometallic Chemistry
      • 43.3 Biological Activity
      • 43.4 Distribution in the Blood
      • 43.5 Intracellular Distribution
      • 43.6 Mechanisms of Action
      • 43.7 Final Remarks
      • Acknowledgments
      • References
    • Chapter 44 Organometallic Chemistry of Rhenium and Technetium Fueled by Biomedical Applications
      • 44.1 Introduction
      • 44.2 Basic Concepts on Nuclear Medicine and Radiopharmaceuticals
      • 44.3 Re(I) and Tc(I) Tricarbonyl Precursors
      • 44.4 Organometallic Building Blocks for the Design of Radiopharmaceuticals
      • 44.5 Perfusion Agents
      • 44.6 Target-Specific Complexes
      • 44.7 Concluding Remarks
      • References
    • Chapter 45 Metal-based Indolobenzazepines and Indoloquinolines: From Moderate cdk Inhibitors to Potential Antitumor Drugs
      • 45.1 Introduction
      • 45.2 Indolobenzazepines as Moderate cdk Inhibitors
      • 45.3 Toward Metal-Based Indolobenzazepines as Potential Anticancer Drugs
      • 45.4 Indolo[3,2-c]Quinolines and Their Metal Complexes
      • 45.5 Outlook
      • Acknowledgments
      • References
    • Chapter 46 Metal-based Chelates and Nanosystems as MRI Contrast Agents
      • 46.1 Introduction
      • 46.2 Magnetic Resonance Imaging
      • 46.3 Contrast Enhancement
      • 46.4 Contrast Agents
      • 46.5 T1 Contrast Agents
      • 46.6 T2 Contrast Agents
      • 46.7 Classification of Contrast Agents
      • 46.8 Nanocarriers
      • References
  • Part VII Organometallic Electrochemistry
    • Chapter 47 Electrochemistry and Supramolecular Interactions of ``Ferrocifen'' Anticancer Drugs with Cyclodextrins and Lipid Bilayers: An Electrochemical Overview
      • 47.1 Introduction
      • 47.2 Deciphering the Activation Sequence of Ferrocifens
      • 47.3 Supramolecular Interactions of Ferrocifens with Cyclodextrins and Lipid Bilayers
      • 47.4 Conclusion
      • Acknowledgments
      • References
    • Chapter 48 Electrochemistry of Fischer Aminocarbene Complexes: Effects of Structure on Redox Properties, Electron Distribution, and Reaction Mechanisms
      • 48.1 Introduction
      • 48.2 Value of Electrochemistry
      • 48.3 Fundamental Electrochemical Behavior of Aminocarbene Complexes
      • 48.4 Basic Group of Aminocarbenes
      • 48.5 Hetaryl Chromium(0) Aminocarbenes
      • 48.6 Mechanistic Investigations
      • 48.7 Comparison of Aminocarbene and Alkoxycarbene Complexes
      • 48.8 Summary
      • References
    • Chapter 49 Electron Transfer-induced Coordination Changes in Organometallic Complexes with Non-innocent Hemilabile Ligands
      • 49.1 Introduction
      • 49.2 Discussion of Results
      • 49.3 Concluding Remarks
      • Acknowledgments
      • References
    • Chapter 50 Redox Potential-Structure Relationships and Parameterization in Characterization and Identification of Organometallic Compounds
      • 50.1 Introduction
      • 50.2 Parameterization of Ligands and Metal Centers
      • 50.3 Final Comments
      • Acknowledgments
      • Abbreviations
      • References
    • Chapter 51 Endohedral Metallofullerenes Today: More and More Versatile Ships in Multiform Bottles-Electrochemistry of X-Ray Characterized Monometallofullerenes
      • 51.1 Introduction
      • 51.2 C60-Monometal Endohedral Metallofullerenes
      • 51.3 C72-Monometal Endohedral Metallofullerenes
      • 51.4 C74-Monometal Endohedral Metallofullerenes
      • 51.5 C80-Monometal Endohedral Metallofullerenes
      • 51.6 C82-Monometal Endohedral Metallofullerenes
      • 51.7 C84-Monometal Endohedral Metallofullerenes
      • 51.8 C90-Monometal Endohedral Metallofullerenes
      • 51.9 C92-Monometal Endohedral Metallofullerenes
      • 51.10 C94-Monometal Endohedral Metallofullerenes
      • 51.11 Conclusion
      • Aknowledgment
      • References
  • Postscript: A Short History of the ICOMC Conferences
  • Index
  • bins

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