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2.1.3.2 Intraband Transition
At the zone center the valence band structure of most semiconductors consists of the
light-hole (LH), the heavy-hole (HH) bands and the split-off (SO) bands. The three
subbands are separated by spin-orbit interaction. In
a p-type semiconductor the
valence band is filled with holes, and the occupancy of the different bands depends on
the degree of doping and the position of the Fermi level. With the right energy of the
incident photons, absorption between different subbands can be observed. However,
these types of transitions are not observed in n-type materials.
2.1.3.3 Free-Carrier Absorption
Free carrier absorption occurs when a material absorbs
a photon and a carrier is
excited from a filled region below the Fermi level to an unoccupied region above the
Fermi level (in the same band). This is different from interband absorption in
semiconductors because the electron being excited is a conduction electron (i.e. it can
move freely). In interband absorption, the electron is being raised from a valence band
to a conducting one. This transition also needs to conserve momentum.
Momentum
conservation is normally provided by optical or acoustic phonons.
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