January-february 2019 Physical properties of reactive rf sputtered a-izon thin films
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0035-001X-rmf-65-02-133
3.3.
Electrical properties Within the characterization of semiconductor materials, one of the most important is undoubtedly the analysis of the elec- trical properties. The density of charge carriers, mobility, type of electrical conductivity and resistivity are fundamen- tal properties in terms of technological applications. There are direct and indirect techniques for measuring the carrier density, in direct techniques we can mention the Hall Effect measurement, which consists of the measurement of a volt- age transverse to the direction of the current flowing through the thin film. This voltage is a result of the interaction of the current with a magnetic field perpendicular to it. On the other hand it is also possible to determine the electrical properties of a thin film by means of the interpretation of the parameters obtained from the model of Drude. The carrier concentration (N) is related to the plasma fre- quency by the equation: N = (ω 2 p m ∗ ² ∞ ² 0 ) e 2 (2) similarly, the mobility (µ) of the charge carriers is related to the Drude resonance width from the equation: µ = e Γ D m ∗ (3) and finally, the resistivity (ρ) that is the inverse of the conduc- tivity is expressed in terms of mobility and the concentration of carriers by means of the following relation: ρ = µ 1 N eµ ¶ (4) 3.3.1. Hall Effect Analysis The carrier concentration, the mobility and the resistivity of the IZON thin films were analyzed as a function of the sput- tering power. Figure 6 shows the dependence of the electrical properties as function of the sputtering power used for the de- position. In each picture are plotted the values directly mea- sured by Hall Effect technique and the calculated values from the obtained SE parameters. For the calculation of the electric properties, an effective mass of 0.3 times the mass of the electron was used, which is F IGURE 6. Electrical properties of IZON films, directly measured by Hall Effect technique (open circles) and the calculated values from the obtained SE parameters (full square). the average value reported for IZON films under similar con- ditions [15]. All of the films presented n-type conductivity, which is the typical conductivity reported for IZON films. Moreover, all the IZON films presented a high carrier con- centration with values over 10 20 cm −3 , independently of the used sputtering power; the highest value obtained correspond to the film deposited at 80 W and the film deposited at lower sputtering power (60 W) had the lowest carrier concentration, the values calculated from Drude parameters were consistent with the directly measured by Hall effect technique. Sim- ilarly, the lowest mobility with a value of 14 cm 2 ·V −1 · s −1 was measured for the film deposited at 60 W, however, for the films grown at 80 W and 100 W the mobility increased until to reach a value maximum of 21 cm 2 ·V −1 · s −1 ; finally, for Rev. Mex. Fis. 65 (2019) 133–138 138 J.J. ORTEGA et al., the sample deposited at 120 W the mobility decreased until it reached a value of 19 cm 2 ·V −1 ·s −1 . Finally, it is seen that the resistivity of the IZON films decreases as a function of sput- tering power and the best value was obtained for the IZON films deposited at 80 W with a value of 7.4 × 10 −3 Ω·cm. As a function of the deposition power the resistivity improves sufficiently for the film deposited at 80 W, reaching values almost equal to those reported for IZO films, however this tendency is not conserved and the resistivity of the films de- posited at 100 and 120 W increased slightly due to the de- crease shown in carrier concentration even when the mobility practically remains constant. Download 0.59 Mb. Do'stlaringiz bilan baham: |
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